Search results for "membrane crystallizer"
showing 4 items of 4 documents
Modelling and experimental investigation of a novel ion exchange membrane crystallizer for magnesium recovery
2020
ION EXCHANGE MEMBRANE CRYSTALLIZER FOR MAGNESIUM RECOVERY FROM SEAWATER AND INDUSTRIAL BRINE
2020
The treatment and valorisation of waste brines deriving from industrial processes raised in the last years a strong interest in order to promote the whole process sustainability both in terms of minimisation of environmental impacts and raw materials recovery within a circular economy approach. With this respect, magnesium recovery from brines can be an interesting and practical example. In this work, a novel ion exchange membrane crystallizer (CrIEM1) is presented. In a CrIEM reactor, the presence of an Anion Exchange Membrane, separating a brine and an alkaline solutions, allows the passage of hydroxyl ions from the alkaline to the brine compartment, where crystallization of magnesium hyd…
A simulation tool for ion exchange membrane crystallization of magnesium hydroxide from waste brine
2021
Abstract Increasing attention is nowadays paid to the management and valorisation of industrial waste brines aiming also at the recovery of raw materials. Magnesium has been listed as a Critical Raw Material by EU, prompting researchers to investigate novel routes for its recovery. Within this framework, a novel Crystallizer with Ion Exchange Membrane (CrIEM), is proposed as an innovative way to recover magnesium from industrial waste brines exploiting low-cost alkaline reactants. In the present work, a novel mathematical model of the CrIEM process is proposed to provide a useful tool for its design in different working conditions. Batch and feed & bleed continuous configurations have been …
A Novel Ionic Exchange Membrane Crystallizer to Recover Magnesium Hydroxide from Seawater and Industrial Brines
2020
A novel technology, the ion exchange membrane crystallizer (CrIEM), that combines reactive and membrane crystallization, was investigated in order to recover high purity magnesium hydroxide from multi-component artificial and natural solutions. In particular, in a CrIEM reactor, the presence of an anion exchange membrane (AEM), which separates two-compartment containing a saline solution and an alkaline solution, allows the passage of hydroxyl ions from the alkaline to the saline solution compartment, where crystallization of magnesium hydroxide occurs, yet avoiding a direct mixing between the solutions feeding the reactor. This enables the use of low-cost reactants (e.g., Ca(OH)2) without …